1/30/2024 0 Comments Core shell atomic layer depositionCompared to the pure SnO 2 NWs, the PL spectrum of the core-shell nanostructures exhibits a stronger emission peak, which suggests potential applications in optoelectronics. In this work, atomic layer deposition (ALD) is utilized to synthesize thermite materials with greatly enhanced reaction rates. The surface steps and defects induced by the lattice mismatch likely lead to improved photoluminescence (PL) performance for the yellow emission. Atomically smooth surfaces are found for growth on the surfaces), the shell also derives an octagonal shape from the epitaxial growth, which was explained by a proposed model based on ALD kinetics. The size and shape of the resulting pores can be tailored by modifying the number of atomic layer deposition cycles. The growth behavior of the TiO 2 shells highly depends on the surface orientations and the geometrical shape of the core SnO 2 NW cross-section. All characterizations, by X-ray diffraction, high-resolution transmission electron microscopy, selected area electron diffraction and Raman spectra, reveal that single crystalline rutile TiO 2 shells can be epitaxially grown on SnO 2 NWs with an atomically sharp interface at low temperature (250 ☌). alumina via ALD on nanocrystal films consisting of CdSe/ZnS core-shell nanoparticles. Abstract Taking TiO 2/SnO 2 core-shell nanowires (NWs) as a model system, we systematically investigate the structure and the morphological evolution of this heterostructure synthesized by atomic layer deposition/epitaxy (ALD/ALE). coating with subsequent atomic layer deposition of alumina.
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1/30/2024 0 Comments Mets manager“You want them to feel good about what they put into today,” Showalter said. Jeff McNeil homered leading off the eighth to provide an insurance run for the Mets, who nearly overcame deficits of 6-1 and 9-5 in the opener thanks to a three-run homer by Pete Alonso and solo shots by Brett Baty and pinch-hitter Eduardo Escobar.ĭavid Robertson worked two scoreless innings in the nightcap for his sixth save - the fourth six-out save of his career. “And it motivates me to keep on trying to do the same and working to do the same.” “It feels really good because I was able to put the team ahead there,” Álvarez said through an interpreter. 212 with 18 strikeouts in his first 52 big league at-bats, doubled to left field off Michael Tonkin. Vogelbach and Mark Canha drew one-out walks from Charlie Morton (3-3) in the bottom half before Álvarez, who is hitting. Drew Smith (2-1) tossed 1 1/3 hitless innings in relief of Tylor Megill, who carried a shutout into the sixth before giving up a three-run double to Eddie Rosario. “We know they’re going to be there all year.”ĭaniel Vogelbach hit an RBI double in the nightcap and Starling Marte had a run-scoring single to stake the Mets to a 2-0 lead. “They’re a good team,” Mets manager Buck Showalter said. The Braves won their fifth straight division title last year after sweeping New York on the final weekend of the regular season. The win was just the second in eight games for the Mets, who snapped a six-game losing streak to their NL East rivals. Sean Murphy had a pair of three-run homers in the opener and Acuña launched a 448-foot home run into the rarely reached third deck at Citi Field, powering the Braves to a 9-8 victory after the teams were rained out the previous two days. exited the nightcap early with a bruised shoulder. NEW YORK (AP) - Francisco Álvarez hit a go-ahead, two-run double in the sixth inning and the New York Mets beat Atlanta 5-3 to split a doubleheader Monday after Braves star Ronald Acuña Jr. 1/29/2024 0 Comments Letter to my addictionInterventions are generally intimate moments with only closely affected family members and friends in attendance, so sharing how you feel is normal and expected. If there have been recent fights related to addiction, for example, using kind words can soften the blow of what is to come while reaffirming that previous bonds are still there. It’s okay to be complimentary addiction doesn’t erase all good traits or turn a good person into a bad person. Describe the person in your own words that relate to how you view them - both before and after addiction - as well as what your relationship means. In the introduction of a letter, state who you are and your relationship to the subject of an intervention. Impact letters can take numerous forms depending on the situation at hand, but in order to maximize efficacy, a specific template is recommended. Cruelty doesn’t inspire positive action, so despite the potentially negative feelings associated with addiction, an impact letter should be sympathetic and supportive, not an opportunity to lay into an already challenged individual. While the subject of the intervention is obviously aware something like a theft occurred, they may not understand the true extent of a problem, for example, if you were unable to pay rent or buy groceries due to missing money.Īn impact letter is designed to impress the reality of the situation upon the subject but isn’t intended to be manipulative, mean or patronizing. An impact letter tends to be both detailed and heartfelt, allowing an opportunity to discuss troubling circumstances as well as specific situations that have caused grief.įor example, if your child is living with an addiction and has stolen money from you, lied to you about substance abuse or betrayed your trust in other ways, an impact letter is a good way to explain the ramifications of these events. What Is an Impact Letter?Īn impact letter is exactly what the name implies: a letter to tell someone struggling with addiction the impact their disease has on others. As such, an impact letter, or a letter summarizing the effects of addiction on both you and your larger social circle, is highly recommended. This is rarely easy on the subject of an intervention many may feel attacked or under immense pressure to act, but seeing the effects negative behavior has on friends and family may be the only measure that makes a difference.įinding the right words, particularly when conveying heartfelt emotions to someone’s face, can get very hard, very quickly, leading to a troubled intervention without the proper preparation. When it appears there is no resolution in sight, an intervention may seem like the only possible opportunity to communicate the real nature of a situation. The pain, stress and pressure that come with watching someone you care about slowly spiral out of control are agonizing, and there’s no good way to reveal your feelings without being met with anger or defensive behavior. When you have a loved one facing addiction, it’s not always easy to vocalize your feelings. Will Insurance Cover Behavioral Treatment?.Beacon Health / Value Options Insurance.Rehab Success Rate – Does It Really Work?.Shatterproof FHE Health (First Responders). ***PLEASE READ THIS DOCUMENT IF YOU FIND SOMETHING OUT OF THE ORDINARY IN PLANET CALYPSO! IT MIGHT PROVIDE THE INFO YOU NEED BEFORE CONTACTING THE SUPPORT DEPARTMENT!***Īdded Hestia Plot city southwest, west of Zychion. If you feel that the possibility of encountering minor issues or bugs directly after a Version Update affects your gameplay to an extent that Entropia Universe is not enjoyable, please wait until the mini-patches have been released and any last minute issues have been resolved. Such issues are often addressed via mini-patches directly after a release and in subsequent patches. Nevertheless, even after extensive testing some issues may arise after release. MindArk and the Planet Partners strive to ensure a smooth and problem-free Version Update. Estate points do not visually update correctly in the information panel.Fast weapons now trigger animations and sounds properly.Fixed an issue causing enemies and pets to sometimes get stuck in animations.Fixed an issue that occasionally caused indoor lighting to appear black.
1/29/2024 0 Comments 3 gallon fish bowlWe are sure this tank will be the most unique decoration in your home. A stylish curved base on the back of the tank goes perfectly with this seamless design. Construction is strongly siliconized on the edges to prevent leaking. This 3-gallon glass fish tank comes in a square shape and has a rimless design. It comes in black color which goes well with all tones and interior styles. If you want a tank for the fishes that will catch everyone’s attention, this aquarium is a perfect choice. One of the most unique aquariums on the market is definitely this Marineland tank. Place this 3-gallon glass aquarium on a stand or commode.īuy On Amazon BEST DECORATION 3-GALLON GLASS FISH TANK Marineland Silhouette Aquarium You can pick moonlight or sunlight mode with different colors. The most amazing part is definitely the LED lights. Add colorful plants and other decoration which will create a most amazing aquatic home for your lovely fishes.įor easier cleaning, this unique betta fish tank has a powerful filter that will keep the environment fresh and healthy. With a measurement of 11.31 x 11.31 x 11.13 inches, this 3-gallon glass fish tank can fit small and mini fish breeds like tetra, betta, or tropical ones. The sturdy tank won’t break easily and it is impact-resistant. At the bottom, there is a black stand so you can easily move this tank from side to side. The aquarium comes in cube shape and it has a seamless and rimless design for a better view from all sides. The aquarium is made of durable materials and we are sure your fishes will enjoy in new habitat for a long time. This fish tank is definitely one of the most beautiful and functional models on the market, and if you’re looking for an attractive design, this is a perfect choice. It is the perfect choice for mini fish breeds.īuy On Amazon Jump To Review 6 Best 3-gallon Glass Fish Tanks BEST OF BEST 3-GALLON GLASS FISH TANK GloFish Betta Shadowbox Aquarium Kit The tank comes in a square shape and it has a beautiful design. It is the perfect choice for corners in your home.īEST WITH FILTER 3-GALLON GLASS FISH TANK The modern aquarium with a seamless and frameless design will easily catch your attention. A modern shape will easily fit on the table. The simple and minimalist design of this tank perfectly matches any home decoration. This model has LED lights at the top for reflection The simple design with a curved front will create the illusion of a bigger space. This sturdy tank has lights with beautiful effects. The unique shape with curves sleek base in black color will look attractive in every living space. Beautiful LED lights are perfect for the night. The modern aquarium in the square shape with a rimless design will catch your attention. 1/29/2024 0 Comments Z432 joinmeWe’ve covered the basics of using from the hosting perspective, but we’d like to end by talking about how this differs from those who are attending using the web interface.įor the most part, the interface is the same as the hosts. The fourth icon shows how many people are in the meeting (including the host), and it can also bring up a participant list, or provide a means to invite others.Īnd finally, the fifth three-dot icon takes you to a settings menu, where you can also access all the Pro features we’ll talk about later.Īttendees don't need an app to use, only a web browser (Image credit: ) Get attendees viewpoint Those with a Pro account can also share a specific application window, and both these options appear if you click on this icon. The third is the video control to enable or disable a camera, if you have one, or replace that video with a shared screen. The second icon is a chat bubble, and they will remain greyed until there is someone else to chat with. While you are waiting for attendees to arrive, you might wish to keep this muted, or you might want to greet those who come by acknowledging them. Depending on how you’ve configured the room, sound can come from a microphone or phone. The first represents audio control, and in our example, the sound is muted with an 'X' on it. To those that have used other conferencing apps, this interface might look very familiar.Īlong the top of the panel is the name of the room being hosted, and below that are five icons. He has good proficiency in Technology transfer, Spectroscopy, Stereochemistry, Synthesis, Polymorphism etc., He suffered a paralytic stroke/ Acute Transverse mylitis in Dec 2007 and is 90 %Paralysed, He is bound to a wheelchair, this seems to have injected feul in him to help chemists all around the world, he is more active than before and is pushing boundaries, He has 100 million plus hits on Google, 2.5 lakh plus connections on all networking sites, 100 Lakh plus views on dozen plus blogs, 227 countries, 7 continents, He makes himself available to all, contact him on +91 9323115463, email Twitter,, He lives and will die for his family, 90% paralysis cannot kill his soul., Notably he has 38 lakh plus views on New Drug Approvals Blog in 227 countries.The interface is very simple to follow (Image credit: ) 4. He has good knowledge of IPM, GMP, Regulatory aspects, he has several International patents published worldwide. His New Drug Approvals, Green Chemistry International, All about drugs, Eurekamoments, Organic spectroscopy international,Įtc in organic chemistry are some most read blogs He has hands on experience in initiation and developing novel routes for drug moleculesĪnd implementation them on commercial scale over a 32 PLUS year tenure till date Feb 2023, Around 35 plus products in his career. His friends call him Open superstar worlddrugtracker. He has worked with notable scientists like Dr K Nagarajan, Dr Ralph Stapel, Prof S Seshadri, etc, He did custom synthesis for major multinationals in his career like BASF, Novartis, Sanofi, etc., He has worked in Discovery, Natural products, Bulk drugs, Generics, Intermediates, Fine chemicals, Neutraceuticals, GMP, Scaleups, etc, he is now helping millions, has 9 million plus hits on Google on all Organic chemistry websites. Total Industry exp 32 plus yrs, Prior to joining Glenmark, he has worked with major multinationals like Hoechst Marion Roussel, now Sanofi, Searle India Ltd, now RPG lifesciences, etc. With GLENMARK LIFE SCIENCES LTD, as CONSUlTANT, Retired from GLENMARK in Jan2022 Research Centre as Principal Scientist, Process Research (bulk actives) at Mahape, Navi Mumbai, India. of India as ADVISOR, earlier assignment was Tropical Disease Priority Review Voucher (1)ĭR ANTHONY MELVIN CRASTO, Born in Mumbai in 1964 and graduated from Mumbai University, Completed his Ph.D from ICT, 1991,Matunga, Mumbai, India, in Organic Chemistry, The thesis topic was Synthesis of Novel Pyrethroid Analogues, Currently he is working with AFRICURE PHARMA, ROW2TECH, NIPER-G, Department of Pharmaceuticals, Ministry of Chemicals and Fertilizers, Govt.New Drug Application Resubmission FDA (5).Marketing authorisation application EU (4).Investigational device exemption (IDE) approval (2).Human medicines European Public Assessment Report EPAR (2).Generating Antibiotic Incentives Now (1). 1/29/2024 0 Comments Watering plants while im away diyThis originates from gardeners' advice that you should water new outdoor plants heavily and deeply, rather than "little and often". But it's not a compelling reason to bottom water houseplants exclusively.Īre you overwatering your plants? - The Signs to look out forģ " Bottom watering encourages strong roots". So this one has definitely has elements of truth to it. If there is water at the bottom, you will then pour this away. But equally, if you chose to top water, you would just wait half an hour and then lift the pot from the outer container. Yes, this likely would help prevent overwatering. If you're bottom watering the idea is that after the growing medium has been fully wetted, you lift the pot, let any excess water drip out, and then put it back into its outer container. This is one of the very best ways to prevent overwatering and root rot, as excess water will simply drain out of the holes and can then be poured away. Most plant parents are encouraged to use pots with drainage holes in the bottom. Bottom watering will never change that.Ģ " Bottom watering prevents overwatering". The roots will only ever absorb the amount of water they need in that given moment. How the water gets into the growing medium, either from the top of the pot or its bottom, doesn't make any difference. When you water a plant, of course you're wetting the soil and roots simultaneously, and a tiny amount of this will start to be absorbed by the plant immediately. The roots will then access this moisture as and when they need it, ideally for a few days, a week or even longer. Much like a battery is designed to absorb and store energy for later use, the primary purpose of watering is to "recharge" the dry growing medium with moisture. Plants will never immediately "drink" or use all the water you add to the potting mix. In this example, " plants only absorb the water they need" really means " the potting mixture will absorb as much water as it can hold". 1/29/2024 0 Comments Burn for mac yosemite(replace N with the disk number from the last command in the previous example, N would be 2). dmg ending on the output file automatically.Īgain and determine the device node assigned to your flash media (e.g. Hdiutil convert -format UDRW -o ~/path/to/target.img ~/path/to/ubuntu.iso img using the convert option of hdiutil e.g., Open the Terminal (in /Applications/Utilities/ or query Terminal in Spotlight).Ĭonvert the. Tip: Drag and drop a file from Finder to Terminal to 'paste' the full path without risking typing errors. It will also change the filesystem that is on the USB stick to make it bootable, so backup all data before continuing. Note: this procedure requires that you create an. But if you prefer to use a USB stick, please follow the instructions below. We would encourage Mac users to download Ubuntu Desktop Edition by burning a CD. Here's some instructions from How to create a bootable USB stick on OS X Checking the hash ensures that the file was not damaged during the download process and is 100% intact. For the current list of Official Ubuntu SHA256 hashes, see the SHA256SUMS file for the release you're using under (and optionally the PGP signatures in the SHA256SUMS.gpg file) hashes for the older MD5 algorithm are in the same directory. For instructions, please see HowToMD5SUM and HowToSHA256SUM. This link ( ) looks like some excellent instructions on downloading, verifying, and burning an iso (on mac/win/ubuntu), and checking the finished DVD, and a link to booting tips too.īefore burning a DVD, it is highly recommended that you verify the md5 sum or sha256 sum (hash) of the. Using md5sum or sha256sum to verify is the standard way. If you've got any dvd-r's or rewritable dvd-rw's around that might be the easiest, there appears to be an easy way to write an iso to a disk in mac.įirst, you should verify that the Ubuntu iso downloaded correctly with no errors. I'm unfamiliar with mac's, but I'd suggest creating a Ubuntu cd/dvd/usb again using a different method. But try "step 10" (reboot with the alt/option key pressed to boot from the usb stick) if you weren't already. You can now quit Terminal and eject the volume.It sounds like the bootable usb pen drive was not created successfully, especially given the "mac told me that he could not use the pen drive" message. When Terminal says that it's done, the volume will have the same name as the installer you downloaded, such as Install macOS Ventura.After the volume is erased, you may see an alert that Terminal would like to access files on a removable volume.Terminal shows the progress as the volume is erased. When prompted, type Y to confirm that you want to erase the volume, then press Return.Terminal doesn't show any characters as you type. When prompted, type your administrator password.If the volume has a different name, replace MyVolume in the command with the name of your volume. Each command assumes that the installer is in your Applications folder, and MyVolume is the name of the USB flash drive or other volume you're using.
Super Mario Bros The Lost Levels Advanced: in this game we will control luigi who must save Princess Peach with the help of Mario, we will have to pass new levels never before seen by a nintendo fan, in the process we will have to solve puzzles to pass the Forgotten levels, this game will have a greater difficulty than the other Mario games, since this game will have more real physics, for example, when we finish a high jump there will be a moment in which our character will automatically go to the right as if he were slipping, the game also contains a new mushroom that will kill us if we touch it so we must be careful, the mushroom will have a skull on the head warning us that it is a dangerous mushroom, the game will have a new style a little more cartoonish with color Stronger but prettier, the characters will be more tender than their previous versions, the game never left China, so only few of us knew it as children here in all of Latin America, the game has several worlds which will be quite a challenge to pass, if you have nothing to do this game will keep you long since it will be one of the most difficult games you will have played. Super Mario World: The Lost Levels Super Mario Omega Pogo Mario Mario Racing Puzzle Mario vs Sonic Puzzle Mario and Luigi Motorbike Puzzle Mario & Luigi Situation Mario Kart Puzzle Mario in Avalanche Super Mario Skyworld Infinite Mario Bros Online Mario?s Strange Quest Mario vs Luigi 4 Mario Bazooka Mario Love Adventure Mario Never Stop Mario Ghosthouse Mario Fast Race Super Mario Bros 3X Mario Triple Challenge Mario Rotate Adventure Super Mario World: The Lost Adventure Episode 2 Mario Car Keys Super Mario World: The Lost Adventure Mario Mushroom Cupcake Mario Spin World Mario Danger Adventure Super Mario Crossover 3.1.21 Mario Gravity Adventure Mario Christmas Challenge Mario New Extreme 2 Super Mario RPG: Legend of the Seven Stars Super Mario All Stars Mario Combat Super Smash Flash Super Mario and the stars 2 Super Mario motorbike Mario: air adventure Super Mario Bros V.2 Super Mario Adventures Kogama: Super Mario Bros Classical Mario Bros Super Mario World Super Mario and the stars 3 Super Mario cart Super Mario Minecraft Runner Yet Another SMW Hack Warios Adventure Super Diagonal Mario 2 Fishy Escape Yoshis Story Super Mario 64 Land Classic Mario World 3: The Finale Super Mario Kart: Crazy Tracks Super Mario Bros: The Lost Levels Enhanced Wario Ware Unfair Mario 2 Super Mario Odyssey 64 Mario Rescues the Golden Mushroom Super Mario World: Archipelago SMW: Return Trip Super Mario Endless World Super Mario Land 2 DX: 6 Golden Coins Super Mario Bros: Christmas Edition Mario Saves Christmas New Super Mario Land New Super Mario World 1: The Twelve Magic Orbs Super Mario Bros 2 Mario Luigi and the 7 Eggs of Peace Super Mario: Daisy?s Kidnapping Super Mario World 2+3: The Essence Star Super Mario Kart R Mario X World Deluxe Marios Return Again Super Mario World 3X Super Mario 64: Multiplayer Super Mario Bros 2: Mega Mario X Super Mario Bros 3 Minecraft Super Mario Edition Super Mario Odyssey Super Mario 7 in 1 Mario Party 3 Super Mario Run 2 Paper Mario Mario Kart 64 3D Super Mario 64 Dr Mario World Super Mario World: Christmas Edition Super Mario Dream World Super Mario World 2+2: Yoshi?s Island New Super Mario Bros Super Mario: The Hooray Fishing Season Super Mario World: Call of Cthulhu Mario Golf: Advance Tour Mario Vs Sonic Exe More Super Mario Kart Super Mario Bros: Enhanced Mario Pinball Land Super Mario Bros: The Early Years Awesome Mario World A Very Super Mario World Another Mario Remastered Super Mario Run Super Mario World: New Mario?s Adventure Super Mario Bros: New Easter World Super Mario Twins Super Mario World 3 Yoshi S Island Super Mario Bros Star Cg Mario Level Pack Super Mario Advance Kogama Super Mario N64 Mushroom Kingdom Mario Craft Mario Kart Super Circuit Super Bowser 64 Super Mario Bros: Two Player Hack Super Huggie Bros Super Mario Bros Movie Super Alfonso Super Oliver World FNF: Mushroom Mayhem Friday Night Funkin Vs Wario Super Marius Wold Super Mario Bros: Road to Infinity Luigi In Sonic Luigis Adventure Return to Yoshis Island 64 Super Mario Wheelie Super Mario 64 Kirby Edition Kaizo Mario World Super Mario World: Luigi Is Villain 100 Rooms of Enemies Super Mario Riders A Super Mario Adventure Mario Gives Up 3 Mario Gives Up 2 Portal Mario 64 Super Mario Bros 2 Player Co-Op Quest Marios Amazing Adventure Super Mario Bros. |
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